During change of $\mathrm{O}_2$ to $\mathrm{O}_2^{-}$ion, the electron adds on which one of the following…
- $\pi^*$ orbital
- $\pi$ orbital
- $\widetilde{\circ}$ orbital
- $\sigma$ orbital
Solution
\(\begin{aligned}
& \sigma(1 s)^2 \sigma^*(1 s)^2 \sigma(2 s)^2 \sigma^*(2 s)^2 \sigma\left(2 p_z\right)^2 \pi\left(2 p_x\right)^2=\pi\left(2 p_y\right)^2 \\
& \pi^*\left(2 p_x\right)^1=\pi^*\left(2 p_y\right)^1
\end{aligned}\)
Thus, the incoming electron will enter in \(\pi^* 2 p_x\) to form \(\mathrm{O}_2\).
Asked in: NEET 2012 (Mains)
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