During change of $\mathrm{O}_2$ to $\mathrm{O}_2^{-}$ion, the electron adds on which one of the following…

During change of $\mathrm{O}_2$ to $\mathrm{O}_2^{-}$ion, the electron adds on which one of the following orbitals?
  1. $\pi^*$ orbital
  2. $\pi$ orbital
  3. $\widetilde{\circ}$ orbital
  4. $\sigma$ orbital

Solution

Electronic configuration of \(\mathrm{O}_2\)
\(\begin{aligned}
& \sigma(1 s)^2 \sigma^*(1 s)^2 \sigma(2 s)^2 \sigma^*(2 s)^2 \sigma\left(2 p_z\right)^2 \pi\left(2 p_x\right)^2=\pi\left(2 p_y\right)^2 \\
& \pi^*\left(2 p_x\right)^1=\pi^*\left(2 p_y\right)^1
\end{aligned}\)
Thus, the incoming electron will enter in \(\pi^* 2 p_x\) to form \(\mathrm{O}_2\).

Asked in: NEET 2012 (Mains)

Practice more Chemical Bonding and Molecular Structure questions on Aicharya