Consider the reaction, $2 \mathrm{A}+\mathrm{B} \rightarrow$ Products When concentration of $\mathrm{B}$…

Consider the reaction, $2 \mathrm{A}+\mathrm{B} \rightarrow$ Products When concentration of $\mathrm{B}$ alone was doubled, the half-life did not change. When the concentration of $\mathrm{A}$ alone was doubled, the rate increased by two times. The unit of rate constant for this reaction is
  1. $\mathrm{L} \mathrm{~mol}^{-1} \mathrm{~s}^{-1}$
  2. no unit
  3. $\mathrm{mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1}$
  4. $\mathrm{s}^{-1}$

Solution

$2 \mathrm{A}+\mathrm{B} \rightarrow$ Product When conc. of $\mathrm{B}$ is doubled, the half life did not change, hence reaction is of first order w.r.t. $\mathrm{B}$. When concentration of $\mathrm{A}$ is doubled, reaction rate is doubled, hence reaction is of first order w.r.t. $\mathrm{A}$. Hence over all order of reaction is $1+1=2$ So, unit of rate constant $\mathrm{mol}^{-1} \mathrm{~lit~s}^{-1}$. Hence, (A) is correct.

Asked in: JEE Main 2007

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