Consider the following dioxide of group 14 1 . C O 2 2 . S i O 2 3 . G e O 2 4 . S n O 2 5 . P b O 2 The…

Consider the following dioxide of group 14

1. CO2

2. SiO2

3. GeO2

4. SnO2

5. PbO2

The basicity of the dioxide alters in the order
  1. CO2>SiO2>GeO2>SnO2>PbO2
  2. CO2<SiO2<GeO2<SnO2<PbO2
  3. CO2<SiO2<GeO2<PbO2<SnO2
  4. CO2<SiO2<SnO2<PbO2<GeO2

Solution

The basicity of the dioxide alters in the order
CO2<SiO2<GeO2<SnO2<PbO2
The basicity increases on moving down the group. Thus, CO2 and SiO2 are purely acidic. GeO2 is not as strongly acidic as SiO2 . It is weakly acidic and weakly basic. SnO2 and PbO2 are definitely amphoteric.

Asked in: JEE-TOPICTESTS-CHEMISTRY

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