Conc. \(\mathrm{HNO}_3\) turns brown on standing due to formation of

Conc. \(\mathrm{HNO}_3\) turns brown on standing due to formation of
  1. NO
  2. \(\mathrm{NO}_2\)
  3. \(\mathrm{N}_2 \mathrm{O}\)
  4. \(\mathrm{N}_2 \mathrm{O}_4\)

Solution

The decomposition of \(\mathrm{HNO}_3\) is represented by the equation. \(4 \mathrm{HNO}_3 \longrightarrow 2 \mathrm{H}_2 \mathrm{O}+4 \mathrm{NO}_2+\mathrm{O}_2\) Due to the formation of nitrogen dioxide, it turns yellow brown. Hence, option (b) is correct.

Asked in: AP EAMCET 2020 (21 Sep Shift 1)

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