Calculate the time needed for reactant to decompose $99.9 \%$ if rate constant of first order reaction is 0…
Calculate the time needed for reactant to decompose $99.9 \%$ if rate constant of first order reaction is 0.576 minute $^{-1}$.
- 8 minutes
- 12 minutes
- 16 minutes
- 20 minutes
Solution
$99.9 \%$ of the reaction is complete.
So, if $[A]_0=100$, then $[A]_{\mathrm{t}}=100-99.9=0.1$
$\begin{aligned}
\mathrm{t} & =\frac{2.303}{\mathrm{k}} \log _{10} \frac{[\mathrm{A}]_0}{[\mathrm{~A}]_4} \\
& =\frac{2.303}{0.576} \log _{10} \frac{100}{0.1}=\frac{2.303}{0.576} \log _{19}(1000) \\
& =\frac{2.303}{0.576} \times 3 \\
& =11.99 \approx 12 \text { minutes }
\end{aligned}$
Asked in: MHT CET 2023 (12 May Shift 1)
Practice more Chemical Kinetics questions on Aicharya