Calculate the rate constant of the first order reaction if $80 \%$ of the reactant reacted in 15 minute.

Calculate the rate constant of the first order reaction if $80 \%$ of the reactant reacted in 15 minute.
  1. 0.11 minute $^{-1}$
  2. 0.22 minute $^{-1}$
  3. 0.34 minute $^{-1}$
  4. 0.42 minute $^{-1}$

Solution

$80 \%$ of the reactant has reacted. So, if $[A]_0=100$, then $[A]_{\mathrm{t}}=100-80=20$ $\begin{aligned} \mathrm{k} & =\frac{2.303}{\mathrm{t}} \log _{10} \frac{[\mathrm{A}]_0}{[\mathrm{~A}]_{\mathrm{t}}} \\ & =\frac{2.303}{15} \log _{10} \frac{100}{20} \\ & =\frac{2.303}{15} \log _{10}(5) \\ & =\frac{2.303}{15} \times 0.699 \\ & =0.1073 \\ & \approx 0.11 \text { minute }^{-1} \end{aligned}$

Asked in: MHT CET 2023 (11 May Shift 2)

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