Calculate the rate constant of the first order reaction if $80 \%$ of the reactant reacted in 15 minute.
Calculate the rate constant of the first order reaction if $80 \%$ of the reactant reacted in 15 minute.
- 0.11 minute $^{-1}$
- 0.22 minute $^{-1}$
- 0.34 minute $^{-1}$
- 0.42 minute $^{-1}$
Solution
$80 \%$ of the reactant has reacted.
So, if $[A]_0=100$, then $[A]_{\mathrm{t}}=100-80=20$
$\begin{aligned}
\mathrm{k} & =\frac{2.303}{\mathrm{t}} \log _{10} \frac{[\mathrm{A}]_0}{[\mathrm{~A}]_{\mathrm{t}}} \\
& =\frac{2.303}{15} \log _{10} \frac{100}{20} \\
& =\frac{2.303}{15} \log _{10}(5) \\
& =\frac{2.303}{15} \times 0.699 \\
& =0.1073 \\
& \approx 0.11 \text { minute }^{-1}
\end{aligned}$
Asked in: MHT CET 2023 (11 May Shift 2)
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