Calculate the pH of buffer solution containing 0.04 M NaF and $0.02 \mathrm{MHF}\left[\mathrm{pK}_a=3 \cdot…

Calculate the pH of buffer solution containing 0.04 M NaF and $0.02 \mathrm{MHF}\left[\mathrm{pK}_a=3 \cdot 142\right]$.
  1. 4.5
  2. 3.4
  3. 2.6
  4. 5.1

Solution

0.04 M NaF and 0.02 M HF forms an acidic buffer. $\begin{aligned} \mathrm{pH} & =\mathrm{pK}_{\mathrm{a}}+\log _{10} \frac{[\text { Salt }]}{[\text { Acid }]} \\ & =3.142+\log _{10} \frac{(0.04)}{(0.02)} \\ & =3.142+0.3010 \\ & =3.44 \approx 3.4 \end{aligned}$

Asked in: MHT CET 2024 (09 May Shift 2)

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