Calculate the pH of buffer solution containing 0:027M weak acid and 0.054 M of its salt with strong base if…

Calculate the pH of buffer solution containing 0:027M weak acid and 0.054 M of its salt with strong base if $\mathrm{pK}_{\mathrm{a}}$ is 4.2 .
  1. 4.5
  2. 3.2
  3. 5.6
  4. 6.4

Solution

For an acidic buffer solution, $\begin{aligned} \mathrm{pH} & =\mathrm{pK}_{\mathrm{a}}+\log _{10} \frac{[\text { Salt }]}{[\text { Acid }]} \\ & =4.2+\log _{10} \frac{0.054}{0.027}=4.2+\log _{10} 2 \\ \therefore \quad \mathrm{pH} & =4.2+0.3010=4.50 \end{aligned}$

Asked in: MHT CET 2024 (03 May Shift 1)

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