Calculate the pH of a buffer solution containing 0.35 M weak acid and 0.70 M of its salt with strong base if…

Calculate the pH of a buffer solution containing 0.35 M weak acid and 0.70 M of its salt with strong base if $\mathrm{pK}_{\mathrm{a}}$ is 4.56 .
  1. 6.11
  2. 3.72
  3. 4.86
  4. 5.65

Solution

For an acidic buffer, $\begin{aligned} \mathrm{pH} & =\mathrm{pK}_{\mathrm{a}}+\log _{10} \frac{[\text { salt }]}{[\text { acid }]} \\ \therefore \quad \mathrm{pH} & =4.56+\log _{10} \frac{0.70}{0.35} \\ & =4.56+\log _{10} 2=4.56+0.3010 \\ & =4.861 \end{aligned}$

Asked in: MHT CET 2024 (04 May Shift 1)

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