Calculate the magnetic moment of $\mathrm{Gd}^{3+}$ ion $(\mathrm{Z}=64)$.

Calculate the magnetic moment of $\mathrm{Gd}^{3+}$ ion $(\mathrm{Z}=64)$.
  1. 7.95
  2. 9.73
  3. 7.89
  4. 7.93

Solution

Gd $(64)=[\mathrm{Xe}] 4 f^{7} 5 d^{1} 6 s^{2}$
$\mathrm{Gd}^{3+}=[\mathrm{Xe}] 4 f^{7} 5 d^{0} 6 s^{0}$
i.e. no. of unpaired electrons $=7$
$\begin{aligned} \mu=& \sqrt{n(n+2)}=\sqrt{7(7+2)} \\ &=\sqrt{63}=7.93 \mathrm{BM} \end{aligned}$

Asked in: JEE-TOPICTESTS-CHEMISTRY

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