Calculate molar mass of an element having density $8.6 \mathrm{~g} \mathrm{~cm}^{-3}$ if it forms bcc…

Calculate molar mass of an element having density $8.6 \mathrm{~g} \mathrm{~cm}^{-3}$ if it forms bcc structure $\left[\mathrm{a}^3 \times \mathrm{N}_{\mathrm{A}}=22.0 \mathrm{~cm}^3 \mathrm{~mol}^{-1}\right]$
  1. $\quad 106.18 \mathrm{~g} \mathrm{~mol}^{-1}$
  2. $94.6 \mathrm{~g} \mathrm{~mol}^{-1}$
  3. $88.25 \mathrm{~g} \mathrm{~mol}^{-1}$
  4. $80.16 \mathrm{~g} \mathrm{~mol}^{-1}$

Solution

For bec unit cell, $\mathrm{n}=2$. $\begin{aligned} & \text { Density }(\rho)=\frac{\mathrm{M} \times \mathrm{n}}{\mathrm{a}^3 \times \mathrm{N}_{\mathrm{A}}} \\ & 8.6 \mathrm{~g} \mathrm{~cm}^{-3}=\frac{\mathrm{M} \times 2}{22 \mathrm{~cm}^3 \mathrm{~mol}^{-1}} \\ \therefore \quad & \mathrm{M}=\frac{8.6 \times 22}{2}=\frac{189.2}{2}=94.6 \mathrm{~g} \mathrm{~mol}^{-1} \end{aligned}$

Asked in: MHT CET 2024 (04 May Shift 1)

Practice more Solid State questions on Aicharya