Calculate $\Delta H^{\circ}$ for the reaction, $\mathrm{Na}_2…

Calculate $\Delta H^{\circ}$ for the reaction, $\mathrm{Na}_2 \mathrm{O}(\mathrm{s})+\mathrm{SO}_3(\mathrm{~g}) \longrightarrow \mathrm{Na}_2 \mathrm{SO}_4(\mathrm{~g})$ given the following :
  1. +823 kJ
  2. –581 kJ
  3. –435 kJ
  4. +531 kJ

Solution

By ' $2 A+\frac{C}{2}-B$ ', we get $\begin{aligned} & \mathrm{Na}_2 \mathrm{O}+\mathrm{SO}_3 \longrightarrow \mathrm{Na}_2 \mathrm{SO}_4 \\ & \Delta H=-2 \times 146+\frac{259}{2}-418 \\ & \text { or } \quad \Delta H=-580.5 \approx-581 \mathrm{~kJ} \end{aligned}$

Asked in: AP EAMCET 2009

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