Calcium phosphide reacts with water to form $\mathrm{Ca}(\mathrm{OH})_2$ and $X$. When $X$ is passed into…

Calcium phosphide reacts with water to form $\mathrm{Ca}(\mathrm{OH})_2$ and $X$. When $X$ is passed into $\mathrm{CuSO}_4$ solution. $Y$ and $\mathrm{H}_2 \mathrm{SO}_4$ are formed. What is $Y$ ?
  1. $\left[\mathrm{Cu}\left(\mathrm{PH}_3\right)_4\right]^{2 *}$
  2. $\left[\mathrm{Cu}\left(\mathrm{PH}_3\right)_6\right]^{2+}$
  3. $\mathrm{Cu}_3 \mathrm{P}_2$
  4. $\mathrm{CuHPO}_4$

Solution

Calcium phosphide reacts with water to form calcium hydroxide and phosphine. $ \begin{aligned} & \mathrm{Ca}_3 \mathrm{P}_2+6 \mathrm{H}_2 \mathrm{O} \longrightarrow 3 \mathrm{Ca}(\mathrm{OH})_2 a q+2 \mathrm{PH}_3(g) \\ & \text { Calcium Water Calcium hydroxide Phosphine } \\ & \text { Phosphide } \\ & \end{aligned} $ Phosphine when passed into $\mathrm{CuSO}_4$ solution, it reacts to produce black precipitate of cupric phosphide and $\mathrm{H}_2 \mathrm{SO}_4$. $ \begin{aligned} & 3 \mathrm{PH}_3+3 \mathrm{CuSO}_4 \longrightarrow \mathrm{Cu}_3 \mathrm{P}_2 \\ & \text { Phosphine Copper sulphate Cupric phosphide } \\ & +3 \mathrm{H}_2 \mathrm{SO}_4 \\& \text { Sulphuric acid }\\ & \end{aligned} $

Asked in: AP EAMCET 2018 (23 Apr Shift 2)

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