Based on VSEPR theory, the number of 90 degree $\mathrm{F}-\mathrm{Br}-\mathrm{F}$ angles in…

Based on VSEPR theory, the number of 90 degree $\mathrm{F}-\mathrm{Br}-\mathrm{F}$ angles in $\mathrm{BrF}_5$ is

Solution

In $\mathrm{BrF}_5$ number of electrons $=6$ $(1 l p+5 b p)$ So, the structure is supposed to be square pyramidal but will be distorted because of additional lp- $b p$ interaction.
Additional $\quad l p-b p$ interaction reduces the all bond angle and do not let any angle to be $90^{\circ}$. Chemical bonding Conceptual IV

Asked in: JEE Advanced 2010 (Paper 1)

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