Attempt either (a) or (b) : (a) (i) What is homologous series ? Which two of the following organic compounds…

Attempt either (a) or (b) : (a) (i) What is homologous series ? Which two of the following organic compounds belong to the same homologous series ? C2H4, C4H10, C3H4, C4H8 (ii) Write the product(s) in the following reactions : (I) CH3–CH2–OH + CH3COOH $\xrightarrow{\text{Acid}}$ (II) C2H5OH + O2 $\xrightarrow{\text{Burning}}$ (iii) Why does micelle formation take place when soap is added to water ? Figure

Solution

(a) (i) • A series of compounds in which the same functional group substitutes for hydrogen in a carbon chain. / Can be represented by a single general formula and successive members differ by -CH2 unit or 14u. • C2H4 and C4H8 belong to the same homologous series/ are alkenes. Acid (ii) (I) CH3 CH2 OH + CH3 COOH → CH3 COOC2 H5 + H2 O Burning (II) C2 H5 OH + 3O2 → 2CO2 + 3H2 O (balancing may be ignored) (iii) The ionic end of soap interacts with water while the carbon chain interacts with oil/dirt. The soap molecules thus form a structure called micelle. OR (b) (i) (I) Propanone/acetone (II) Propyne (ii) Hydrogenation/addition reaction. (iii) C4H10 will have higher melting point, as it has a higher molecular mass than C3H8 and melting point increases with the increase in molecular mass. (iv) Sodium ethoxide (C2H5ONa) is formed and hydrogen gas is evolved. / (balancing may be ignored) (v) CH3COON C2H5 + NaOH →CH3COONa + C2H5OH ½+ ½ SECTION – C (Physics)

Asked in: CBSE

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