Assertion : $p-\mathrm{O}_2 \mathrm{~N}-\mathrm{C}_6 \mathrm{H}_5 \mathrm{COCH}_3$ is prepared by Friedel…

Assertion : $p-\mathrm{O}_2 \mathrm{~N}-\mathrm{C}_6 \mathrm{H}_5 \mathrm{COCH}_3$ is prepared by Friedel Crafts acylation of nitrobenzene. Reason : Nitrobenzene easily undergoes electrophilic substitution reaction.
  1. If both assertion and reason are true and reason is the correct explanation of assertion
  2. If both assertion and reason are true but reason is not the correct explanation of assertion
  3. If assertion is true but reason is false
  4. If both assertion and reason are false.

Solution

The nitro group strongly deactivates the benzene ring towards electrophilic substitution. Nitrobenzene does not undergo Friedel-Craft acylation reaction.

Asked in: NEET 2003

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