Assertion : $\mathrm{HC} \equiv \mathrm{C}^{-}$is more stable than $\mathrm{H}_2 \mathrm{C}=\mathrm{CH}^{-}$…

Assertion : $\mathrm{HC} \equiv \mathrm{C}^{-}$is more stable than $\mathrm{H}_2 \mathrm{C}=\mathrm{CH}^{-}$.Reason : $\mathrm{HC} \equiv \mathrm{C}^{-}$has more s-character than $\mathrm{H}_2 \mathrm{C}=\mathrm{CH}^{-}$
  1. If both assertion and reason are true and reason is the correct explanation of assertion
  2. If both assertion and reason are true but reason is not the correct explanation of assertion
  3. If assertion is true but reason is false
  4. If both assertion and reason are false.

Solution

$\mathrm{HC} \equiv \mathrm{C}^{-}$has $50 \%$ s-character and $\mathrm{H}_2 \mathrm{C}=\mathrm{CH}^{-}$has $33 \%$ s-character. Stability of carbanions increases with an increase in the s-character at the carbanion. So $\mathrm{HC} \equiv \mathrm{C}^{-}$is more stable than $\mathrm{H}_2 \mathrm{C}=\mathrm{CH}^{-}$.

Asked in: NEET 2019 (All India)

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