Assertion (A) Covalent character follows $\mathrm{NaCl} < \mathrm{MgCl}_2 < \mathrm{BeCl}_2 < \mathrm{LiCl}$…

Assertion (A) Covalent character follows $\mathrm{NaCl} < \mathrm{MgCl}_2 < \mathrm{BeCl}_2 < \mathrm{LiCl}$. Reason (R) According to Fajan's rules, covalent character of ionic compounds increases with decrease in size of cation.
  1. Both $A$ and $R$ are true and $R$ is a correct explanation for $A$.
  2. Both $A$ and $R$ are true but $R$ is not a correct explanation for $\mathrm{A}$.
  3. $A$ is true but $R$ is false.
  4. $A$ is false but $R$ is true.

Solution

The correct order of covalent character is $\mathrm{NaCl} < \mathrm{LiCl} < \mathrm{MgCl}_2 < \mathrm{BeCl}_2$. The covalent character depends on small size as well as more + ve charge on cation.

Asked in: AP EAMCET 2021 (23 Aug Shift 2)

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