As the quantum number increases, the difference in energy between consecutive energy levels

As the quantum number increases, the difference in energy between consecutive energy levels
  1. Remains the same
  2. Increases
  3. Decreases
  4. Sometimes increases and sometimes decreases

Solution

$E_{n+1}-E_n=13.6\left[\frac{1}{n^2}-\frac{1}{(n+1)^2}\right]$ $\begin{aligned} & \Delta \mathrm{E}_{\mathrm{n}}=13.6\left[\frac{(\mathrm{n}+1)^2-\mathrm{n}^2}{\mathrm{n}^2(\mathrm{n}+1)^2}\right] \\ & =13.6\left[\frac{1+2 \mathrm{n}}{\mathrm{n}^2(\mathrm{n}+1)^2}\right]\end{aligned}$ For large value of $n$ $\Delta \mathrm{E}_{\mathrm{n}}=13.6\left[\frac{2 \mathrm{n}}{\mathrm{n}^4}\right]$ $\begin{aligned} & \propto \frac{1}{\mathrm{n}^3} \\ & \text { So, } \mathrm{n} \uparrow \uparrow \Rightarrow \Delta \mathrm{E}_{\mathrm{n}} \downarrow \downarrow\end{aligned}$

Asked in: AP EAMCET 2022 (08 Jul Shift 1)

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