Arrange the following species in the correct order of their stabilities $\mathrm{N}_2^{-}, \mathrm{C}_2,…

Arrange the following species in the correct order of their stabilities $\mathrm{N}_2^{-}, \mathrm{C}_2, \mathrm{Ne}_2, \mathrm{O}_2^{2-}$
  1. $\mathrm{Ne}_2 < \mathrm{O}_2^{2-} < \mathrm{C}_2 < \mathrm{N}_2^{-}$
  2. $\mathrm{Ne}_2 < \mathrm{C}_2 < \mathrm{O}_2^{2-} < \mathrm{N}_2^{-}$
  3. $\mathrm{Ne}_2 < \mathrm{N}_2^{-} < \mathrm{O}_2^{2-} < \mathrm{C}_2$
  4. $\mathrm{Ne}_2 < \mathrm{O}_2^{2-} < \mathrm{N}_2^{-} < \mathrm{C}_2$

Solution

Higher the bond order, more is the stability. The bond order of the given species can be calculated as (i) $\mathrm{N}_2^{-}=$Diatomic molecule Number of electrons $=(7+7+1)=15 e^{-}$ i.e. B.O. = 2.5 (ii) $\mathrm{C}_2=$ Diatomic molecule Number of electrons $=(6+6)=12 e^{-}$ i.e. $ \text { B.O. }=2.0 $ (iii) $\mathrm{Ne}_2=$ Number of bonding and antibonding electrons are equal i.e. B.O. $=0$ $\therefore \mathrm{Ne}_2$ does not exist. (iv) $\mathrm{O}_2^{2-}=$ Diatomic molecule Number of electrons $=(8+8+2) e^{-}=18 e^{-}$ i.e. B.O. $=1.0$ Hence, correct sequence of B.O. is Hence, correct sequence of B.O. is $ \underset{2.5}{\mathrm{~N}_2^{-}}>\underset{2.0}{\mathrm{C}_2}>\underset{1.0}{\mathrm{O}_2^{2-}}>\underset{0}{\mathrm{Ne}_2 .} $ Order of stability is $\mathrm{N}_2^{-}>\mathrm{C}_2>\mathrm{O}_2^{2-}>\mathrm{Ne}_2$

Asked in: AP EAMCET 2021 (25 Aug Shift 2)

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