
Arrange the following organic halides in correct order of reactivity towards \(\mathrm{S}_{\mathrm{N}} 2\)…

- \(P > Q > R\)
- \(R > P > Q\)
- \(P > R > Q\)
- \(Q > R > P\)
Solution

\(3^{\circ}\) alkyl halide (highly sterically hindered)

\(1^{\circ}\) alkyl halide (least sterically hindered)

(R) \(2^{\circ}\) alkyl halide Rate of \(\mathrm{S}_{\mathrm{N}} 2\) reaction \(\propto \frac{1}{\text { sterically hindrance }}\) \(\therefore\) Rate is \(1^{\circ} > 2^{\circ} > 3^{\circ}\) alkyl halide. Hence, \(Q > R > P\) is correct answer.
Asked in: AP EAMCET 2019 (20 Apr Shift 1)