Arrange the following ligand in the order of increasing field strength. H 2 O CO NH 3 I - F - I II III IV V

Arrange the following ligand in the order of increasing field strength.

H2OCONH3I-F-IIIIIIIVV

  1. IV<V<I<III<II
  2. IV<V<III<II<I
  3. V<IV<III<I<II
  4. IV<I<V<II<III

Solution

Spectrochemical series: A list of ligands ordered in ligand strength and a list of metal ions based on oxidation number, group, and identity.

Using the concept of spectrochemical series, the ligands arranged in increasing order of crystal field strength are,

I-<F-<H2O<NH3<CO

If in a complex, at least one ligand is strong field ligand, in this case, all ligands are considered as strong field ligand.

Asked in: AP EAMCET 2018 (25 Apr Shift 1)

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