An ideal gas is subjected to cyclic process involving four thermodynamic states, the amounts of heat (Q) and…

An ideal gas is subjected to cyclic process involving four thermodynamic states, the amounts of heat (Q) and work (W) involved in each of these states $Q_{1}=6000 \mathrm{~J} ; Q_{2}=-5500 \mathrm{~J} ; \quad Q_{3}=-3000 \mathrm{~J}$
$Q_{4}=+3500 \mathrm{~J}$
$W_{1}=2500 \mathrm{~J} ; \quad W_{2}=-1000 \mathrm{~J} ; \quad W_{3}=-1200 \mathrm{~J}$
$W_{4}=x \mathrm{~J}$
The ratio of the net work done by the gas to the total heat absorbed by the gas is $\eta$. The values
of $x$ and $\eta$ respectively are
  1. $500 ; 7.5 \%$
  2. $700 ; 10.5 \%$
  3. $1000 ; 21 \%$
  4. $1500 ; 15 \%$

Solution

$Q=Q_{1}+Q_{2}+Q_{3}+Q_{4}$
$=6000-5500-3000+3500=+1000 \mathrm{~J}$
$W=W_{1}+W_{2}+W_{3}+W_{4}$
$=2500-1000-1200+x=+300+x$
In cyclic process, $\Delta U=0$ Now, $Q=\Delta U+W$
or $1000=0+(300+x)$
$\therefore x=700 \mathrm{~J}$
$\eta=\frac{W}{Q_{1}+Q_{4}}$
$=\quad \frac{1000}{6000+3500}=10.5 \%$ ^

Asked in: JEE-TOPICTESTS-CHEMISTRY

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