Among the following species the one which causes the highest CFSE, $\Delta_0$ as a ligand is:

Among the following species the one which causes the highest CFSE, $\Delta_0$ as a ligand is:
  1. $\mathrm{CN}^{-}$
  2. $\mathrm{NH}_3$
  3. $\mathrm{F}^{-}$
  4. $\mathrm{CO}$

Solution

Following is the order of increasing value of $\Delta_0$ for the ligands. $ \begin{aligned} &\mathrm{I}^{-} < \mathrm{Br}^{-} < \mathrm{Cl}^{-} < \mathrm{F}^{-} < \mathrm{H}_2 \mathrm{O} < \mathrm{Py}=\mathrm{NH}_3 < \text { en } \\ & < \mathrm{NO}_2-< < \mathrm{CN}^{-} < \mathrm{CO} \end{aligned} $

Asked in: JEE Main 2014 (12 Apr Online)

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