Among the following species, the diamagnetic molecule is:

Among the following species, the diamagnetic molecule is:
  1. CO
  2. B2
  3. O2
  4. NO

Solution

(1) B2(10)σ1s2,σ*1s2,σ2s2,σ*2s2,π2px1=π2py1 , paramagnetic
(2) NO15σ1s2σ*1s2σ*2s2σ2pz2π2px2=π2py2=π*2px1 , paramagnetic
(3) O216 σ1s2σ*1s2σ2s2σ*2pz2π2px2=π2py2π*2px1=π*2py, paramagnetic
(4) CO14  σ1s2σ*1s2,σ2s2,σ*2s2,πpx2=π2py2,σ2pz2, diamagnetic (No unpaired electron)

Asked in: JEE Main 2019 (09 Apr Shift 2)

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