Alkyl halide reacts with an alcoholic solution of ammonia to give a mixture of:

Alkyl halide reacts with an alcoholic solution of ammonia to give a mixture of:
  1. $1^{\circ}$ and $2^{\circ}$ amine
  2. $1^{\circ}, 2^{\circ}, 3^{\circ} \&$ quarternary
  3. $1^{\circ}, 2^{\circ} \& 3^{\circ}$ amines
  4. $1^{\circ} \& 3^{\circ}$ amine

Solution

Acoholic solution of ammonia is heated in a sealed tube at 100${ }^{\circ} \mathrm{C}$
$\mathrm{RI} \stackrel{\mathrm{NH}_{3}}{\longrightarrow} \underset{1^{\circ} \text { amine }}{\mathrm{RNH}_{2}} \stackrel{\mathrm{RI}}{\longrightarrow} \underset{2^{\circ} \text { amine }}{(\mathrm{R})_{2} \mathrm{NH}} \stackrel{\mathrm{RI}}{\longrightarrow} \underset{3^{\circ}{ }^{\circ} \mathrm{amine}}{(\mathrm{R})_{3} \mathrm{~N} }\stackrel{\mathrm{RI}}{\longrightarrow}(\mathrm{R})_{4} \underset{4^{\circ} \mathrm{amine}}{\mathrm{N}^{+} \mathrm{I}^{-}}$ ^

Asked in: JEE-TOPICTESTS-CHEMISTRY

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