According to MO theory, number of species/ions from the following having identical bond order is____ CN - ,…

According to MO theory, number of species/ions from the following having identical bond order is____

CN-,NO+,O2,O2+,O22+

Solution

The bond order of a diatomic species can be calculated using molecular orbital theory as follows,

Bond order=No.of BMO electrons-No.of ABMO electrons2

BMO = bonding molecular orbital

ABMO = Anti bonding molecular orbital.

Based on the total number electrons in bond orders are given in the following table.

Number of e- Bond order
13 2.5
14 3
15 2.5
16 2

CN- , NO+ and O22+ are having 14 electrons each, hence the bond order is 3.

Asked in: JEE Main 2022 (27 Jul Shift 1)

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