A solution of $(+)-2$ - chloro $-2$ - phenylethane in toluene racemises slowly in the presence of small…

A solution of $(+)-2$ - chloro $-2$ - phenylethane in toluene racemises slowly in the presence of small amounts of $\mathrm{SbCl}_{5}$ due to the formation of
  1. Carbanion
  2. Carbene
  3. Free radical
  4. Carbocation

Solution

$\mathrm{SbCl}_{5}$ pulls $\mathrm{Cl}^{-}$ to form $\mathrm{SbCl}_{6}^{-}$ leaving behind planar $\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}^{+}-\mathrm{CH}_{3}$ carbonium ion. It
can be attacked from either side leading to racemic mixture. /

Asked in: JEE-TOPICTESTS-CHEMISTRY

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