A solute A dimerizes in water. The boiling point of a 2 molal solution of A is 100 . 52 C ∘ . The…

A solute A dimerizes in water. The boiling point of a 2 molal solution of A is 100.52C. The percentage association of A is ___ .
(Round off to the Nearest integer)

 Use : Kb for water =0.52 K kg mol-1 

            Boiling point of water =100°C

Solution

ΔTb=Tb-Tb0

100.52-100

=0.52°C

i=1-α2

ΔTb=iKb×m

0.52=1-α2×0.52×2

α=1

So, percentage association =100%.

Asked in: JEE Main 2021 (18 Mar Shift 2)

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