A smuggler could not carry gold by depositing iron on the gold surface since

A smuggler could not carry gold by depositing iron on the gold surface since
  1. gold is denser
  2. iron rusts
  3. gold has higher reduction potential than iron
  4. gold has lower reduction potential than iron

Solution

Gold having higher $E_{\text {Red }}^{0}$ and oxidises $\mathrm{Fe} \longrightarrow \mathrm{Fe}^{2+}$ Gold has a reduction potential \(=+1.5 \mathrm{~V}\). Iron has a reduction potential \(=-0.44 \mathrm{~V}\). Thus, gold has a higher reduction potential than iron. An element with a higher reduction potential is a stronger oxidizing agent. So, gold is a stronger oxidizing agent than iron. Hence, gold will get reduced itself instead of iron. Therefore, iron can not be deposited on the gold surface. ^

Asked in: JEE-TOPICTESTS-CHEMISTRY

Practice more ELECTROCHEMISTRY questions on Aicharya