A pure Si crystal has $4 \times 10^{28}$ atoms per $\mathrm{m}^3$. It is doped by $1 \mathrm{ppm}$…

A pure Si crystal has $4 \times 10^{28}$ atoms per $\mathrm{m}^3$. It is doped by $1 \mathrm{ppm}$ concentration of antimony. The number of free electrons available will be
  1. $4 \times 10^{34} \mathrm{~m}^{-3}$
  2. $4 \times 10^{28} \mathrm{~m}^{-3}$
  3. $4 \times 10^{22} \mathrm{~m}^{-3}$
  4. $4 \times 10^{20} \mathrm{~m}^{-3}$.

Solution

Given: Density of Si atoms $=4 \times 10^{28}$ atoms $/ \mathrm{m}^3$ After doping with $1 \mathrm{ppm}$ of Sb, $\begin{aligned} \text { No. of Sb atoms } & =\frac{4 \times 10^{28}}{10^6} \\ & =4 \times 10^{22} \end{aligned}$ The above number of $\mathrm{Sb}$ atoms donates 1 electron each. $\therefore \quad$ The total number of free electrons will be $4 \times 10^{22} \mathrm{~m}^{-3}$

Asked in: MHT CET 2023 (10 May Shift 2)

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