A molecule undergoes two independent first order reactions whose respective half lives are 12   min and…

A molecule undergoes two independent first order reactions whose respective half lives are 12 min and 3 min. If both the reactions are occurring then the time taken for the 50% consumption of the reactant is ______ min. (Nearest integer)

Solution

For parallel reaction

When adding the rate constants of the two reactions, we need to use the formula for combining rate constants of two reactions in parallel, which is:

k=k1+k2

where k1 and k2 are the rate constants of the individual reactions.

In this case, the half-lives of the two reactions are 12 min and 3 min, respectively. The rate constants of the two reactions can be calculated using the formula for half-life of a first-order reaction:

1t1/2=112+13=512

Net t1/2=125=2.4 min2 min

Hence time taken for 50% consumption of reactant will be close to 2 min.

Asked in: JEE Main 2023 (10 Apr Shift 1)

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