(a) (i) Draw two isomeric structures of Butene (C4H8). (ii) Name the following compounds : (I) H-C-C-C-Cl…

(a) (i) Draw two isomeric structures of Butene (C4H8). (ii) Name the following compounds : (I) H-C-C-C-Cl chain, each carbon bearing H atoms as substituents, with Cl on the terminal carbon (three-carbon chain: CH3-CH2-CH2-Cl type structure, all bonds single). (II) A four-carbon chain H-C-C-C-C-H with H substituents on the first three carbons and a double-bonded O on the fourth carbon (aldehyde-type structure). (iii) Write the chemical equations for the following reactions. Mention one essential condition each for these reactions to take place. (I) Ethanol undergoes complete oxidation (II) Propene undergoes hydrogenation (III) Ethanoic acid reacts with ethanol Figure

Solution

(a) (i) Β½, Β½ (any two) (ii) (I) Chloropropane (II) Butanone/ Butan-2-one (iii) (I) (II) CH3CH=CH2 + H2 CH3CH2CH3 𝐴𝑐𝑖𝑑 (III) 𝐢𝐻3 𝐢𝑂𝑂𝐻 + 𝐢2 𝐻5 𝑂𝐻 β†’ 𝐢𝐻3 𝐢𝑂𝑂𝐢2 𝐻5 + 𝐻2 𝑂 OR (b) (i) X = Ethanol/ Ethyl alcohol/ C2H5OH Y = Sodium ethoxide/ C2H5ONa Z = Hydrogen/H2 𝐢𝐻3 𝐢𝐻2 𝑂𝐻 + π‘π‘Ž β†’ 𝐢𝐻3 𝐢𝐻2 π‘‚π‘π‘Ž + 𝐻2 X Y Z (ii) (I) (II) Page 8 of 12 X_086_ 31/1/1 (III) (No mark to be deducted if equations are not balanced.)

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