(a) (i) Draw two isomeric structures of Butene (C4H8). (ii) Name the following compounds : (I) H-C-C-C-Clβ¦
(a) (i) Draw two isomeric structures of Butene (C4H8). (ii) Name the following compounds : (I) H-C-C-C-Cl chain, each carbon bearing H atoms as substituents, with Cl on the terminal carbon (three-carbon chain: CH3-CH2-CH2-Cl type structure, all bonds single). (II) A four-carbon chain H-C-C-C-C-H with H substituents on the first three carbons and a double-bonded O on the fourth carbon (aldehyde-type structure). (iii) Write the chemical equations for the following reactions. Mention one essential condition each for these reactions to take place. (I) Ethanol undergoes complete oxidation (II) Propene undergoes hydrogenation (III) Ethanoic acid reacts with ethanol
Solution
(a)
(i)
Β½, Β½
(any two)
(ii) (I) Chloropropane
(II) Butanone/ Butan-2-one
(iii) (I)
(II)
CH3CH=CH2 + H2 CH3CH2CH3
π΄πππ
(III) πΆπ»3 πΆπππ» + πΆ2 π»5 ππ» β πΆπ»3 πΆπππΆ2 π»5 + π»2 π
OR
(b)
(i) X = Ethanol/ Ethyl alcohol/ C2H5OH
Y = Sodium ethoxide/ C2H5ONa
Z = Hydrogen/H2
πΆπ»3 πΆπ»2 ππ» + ππ β πΆπ»3 πΆπ»2 πππ + π»2
X Y Z
(ii)
(I)
(II)
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(III)
(No mark to be deducted if equations are not balanced.)