A compound $A$ contains $C$ and $H$ only and has molecular mass 72. It's photochlorination gives a mixture…

A compound $A$ contains $C$ and $H$ only and has molecular mass 72. It's photochlorination gives a mixture containing only one monochloro and two dichloro hydrocarbons. The IUPAC name is
  1. 2, 2-dimethylpropane
  2. n-pentane
  3. 2-methyl butane
  4. cyclopentane

Solution

$\mathrm{C}_5 \mathrm{H}_{12}$, pentane has molecular mass $72 \mathrm{~g}$ i.e. the isomer of pentane which yields single monochloro derivative and two dichloro derivative is 2, 2-dimethyl propane as it has all equivalent hydrogens.

Asked in: AP EAMCET 2021 (23 Aug Shift 1)

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