A closed container contains a homogeneous mixture of two moles of an ideal monatomic gas γ = 5 3 and…

A closed container contains a homogeneous mixture of two moles of an ideal monatomic gas γ=53 and one mole of an ideal diatomic gas γ=75. Here, γ is the ratio of the specific heats at constant pressure and constant volume of an ideal gas. The gas mixture does a work of 66 Joule when heated at constant pressure. The change in its internal energy is _____ Joule.

Solution

Change in internal energy for the mixture can be written as,U=n1Cv1T+n2Cv2T

=n1Cv1+n2Cv2T     ...i

For isobaric process, work done =PV

=n1+n2RT      ...ii

Divide i by ii, we get

UW=n1Cv1+n2Cv2Tn1+n2RT

U=WRn1Cv1+n2Cv2n1+n2

=66R2×3R2+1×5R22+1

=121 J

.

Asked in: JEE Advanced 2023 (Paper 1)

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