A buffer solution is prepared by mixing $0.2 \mathrm{M}$ sodium acetate and $0.1 \mathrm{M}$ acetic acid. If…

A buffer solution is prepared by mixing $0.2 \mathrm{M}$ sodium acetate and $0.1 \mathrm{M}$ acetic acid. If $\mathrm{pK}_{\mathrm{a}}$ for acetic acid is 4.7 , find the $\mathrm{pH}$.
  1. 3.0
  2. 4.0
  3. 5.0
  4. 2.0

Solution

Using Henderson's equation, $\begin{aligned} & \mathrm{pH}=\mathrm{pK}_{\mathrm{a}}+\log _{10} \frac{[\text { Salt }]}{[\text { Acid }]} \\ & \mathrm{pH}=4.7+\log _{10} \frac{0.2}{0.1} \\ & \mathrm{pH}=4.7+\log _{10} 2=4.7+0.3010=5.001 \end{aligned}$

Asked in: MHT CET 2023 (09 May Shift 1)

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