A 0 . 120 molal solution of CsCl [ with ionizes in the solution as CsCl ⇌ Cs + + Cl - ] freezes at - 0…

A 0.120 molal solution of CsCl [with ionizes in the solution as CsClCs++Cl-] freezes at -0.4°C. The Van't Hoff factor and degree of dissociation of CsCl in the solution, respectively, are

(Given Kfwater=1.86 K kg mol-1)

  1. 1.79, 0.79
  2. 1.5, 0.5
  3. 1.92, 0.92
  4. 1.2, 0.2

Solution

ΔTf=i×kf×m

Tf°-Tf=1.86×i×0.120

0.4=i×0.2232

i=1.79

i=1+(n-1)α n=2

1.79=1+α

,

Asked in: JEE-TOPICTESTS-CHEMISTRY

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