50   mL of 0 . 1   M   CH 3 COOH is being titrated against 0 . 1   M   NaOH . When…

50 mL of 0.1 M CH3COOH is being titrated against 0.1 M NaOH. When 25 mL of NaOH has been added, the pH of the solution will be____×10-2. (Nearest integer)

(Given : pKaCH3COOH=4.76)

log2=0.30

log3=0.48

log5=0.69

log7=0.84

log11=1.04

Solution

CH3COOHaq+NaOHaq.CH3COONaaq+H2Ol

5 mmole              2.5 mmoles                                                     initially2.5 m moles            0                           2.5 mmoles              after reaction

Resultant solution is acidic buffer solution with same concentration of acid and salts.

pH = pKa + log[salt][acid]

So, pH of solution pH=pKa=4.76=476×10-2

Asked in: JEE Main 2022 (26 Jun Shift 1)

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