200   mL of 0 . 2   M   HCl is mixed with 300   mL of 0 . 1   M   NaOH . The…

200 mL of 0.2 M HCl is mixed with 300 mL of 0.1 M NaOH. The molar heat of neutralization of this reaction is -57.1 kJ. The increase in temperature in C of the system on mixing is x×10-2. The value of x is (Nearest integer)

[Given: Specific heat of water =4.18 J g-1 K-1 

Density of water=1.00 g cm-3]

(Assume no volume change on mixing)

Solution

milimole HCl400+NaOH300NaCl-30+H2O-- ΔHneut =-57.1KJ

ΔH=-57.1×30×10-3×103J=1713 J

q=m·s.ΔT

1713=500×4.18×ΔT

ΔT=0.8196 K=81.96×10-2 K82×10-2 K

Asked in: JEE Main 2021 (27 Aug Shift 1)

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