20   mL of 0 . 1 M   NH 4 OH is mixed with 40   mL of 0 . 05   M   HCl . The pH of…

20 mL of 0.1M NH4OH is mixed with 40 mL of 0.05 M HCl. The pH of the mixture is nearest to:
(Given: KbNH4OH=1×10-5, log2=0.30, log3=0.48, log5=0.69, log7=0.84log11=1.04)
  1. 3.2
  2. 4.2
  3. 5.2
  4. 6.2

Solution

            NH4OH+HClNH4Cl+H2Ommole  2          2after reaction -    -           2 milimoles

NH4+=2 mmole60 ml=130M

pH=pKw-pKb-logC2=14-5+1.482=5.24

Asked in: JEE Main 2022 (25 Jul Shift 1)

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