20   mL of 0 . 02   M hypo solution is used for the titration of 10   mL of copper sulphate…

20 mL of 0.02 M hypo solution is used for the titration of 10 mL of copper sulphate solution, in the presence of excess of KI using starch as an indicator. The molarity of Cu2+ is found to be _____×10-2M (nearest integer)

Given : 2Cu2++4I-Cu2I2+I2I2 + 2S2O3-2    2I + S4O6-2

Solution

neq. of I2=neq of Na2 S2O3=20×0.02×10-3

2×nmol of I2=0.4 ×10-3

nmol of I2=0.2 m mol

nmol of Cu+2=0.2×2×10-3

Cu+2=0.4×10-310×10-3=0.04=4×10-2

Asked in: JEE Main 2022 (26 Jul Shift 2)

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