1   g of a non-volatile non-electrolyte solute is dissolved in 100   g of two different solvents A…

1 g of a non-volatile non-electrolyte solute is dissolved in 100 g of two different solvents A and B whose ebullioscopic constants are in the ratio of 1:5. The ratio of the elevation in their boiling points, TbATbB, is: (assuming they have the same molar mass)
  1. 10:1
  2. 1:5
  3. 1:0.2
  4. 5:1

Solution

Elevation in Boiling point  Tb=i×kb×m

For non-electrolyte, i=1

m= Molar mass of solute

m1=molality of solution 1m2= molality of solution 2

Tb1=k1×1×m1, m1=1100×m×1000=10m

Tb2=k2×1×m2, m2=1100×m×1000=10m

m1=m2 

Tb1Tb2=k1k2=1:5

Asked in: JEE Main 2019 (10 Apr Shift 2)

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