0 . 25   g of an organic compound containing chlorine gave 0 . 40   g of silver chloride in Carius…

0.25 g of an organic compound containing chlorine gave 0.40 g of silver chloride in Carius estimation. The percentage of chlorine present in the compound is [in nearest integer]
(Given: Molar mass of Ag is 108 g mol-1 and that of Cl is 35.5 g mol-1)

Solution

Percentage of chlorine in the organic compound=atomic mass of chlorine X mass of AgCl formed X 100molecular mass ofAgCl X weight of organic compound

Mass of organic compound =0.25 g

Mass of AgCl formed =0.40 g

Mass of Cl in organic compound =0.40×35.5143.5×0.25

Percentage of Cl in the compound =0.40×35.5143.5×0.25×100

=39.58%

Nearest integer=40.

Asked in: JEE Main 2022 (27 Jun Shift 2)

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